广州彬荣化工有限公司
立德粉 , 钛白粉 , 硬脂酸锌 , 硬脂酸钙 , 硬脂酸镁 , 硬脂酸钡
韶关韶冶氧化锌 南华牌 南华

产品图片

 

产品特点及用途product characteristics and uses

产品名称 

 氧化锌

 产品英文名 

 zinc oxide;zinc white

 产品别名 

  锌氧粉;锌白

 分子式 

 zno

 产品用途 

 用作油漆颜料和橡胶的填充剂

 cas号 

 1314-13-2

 毒性防护 

  中毒者会出现食欲不佳、烦渴、疲倦、胸闷及压痛、嗜睡、干咳、并出现体温升高、瞳孔扩大、结膜及咽部、面部充血、糖尿,有时还出现肝大。重者出现肺间质水肿,肺泡上皮破坏。 发生中毒可吸入碱性物质、静脉注射葡萄糖(40%溶液20ml)和300mg抗坏血酸。根据症状服用强心剂。空气中Zui高容许浓度0.5mg/m3。 操作中应戴防毒口罩,防护眼镜,穿工作服。工作后热水沐浴。要注意防止蒸气及气溶胶形成及排放到工作地点空气中。应注意防尘通风。

 包装储运 

 用内衬2~3层80克牛皮纸或聚乙烯塑料袋的编织袋包装,每袋净重25kg、30kg。 贮存于通风、阴凉、干燥的库房中。包装要密封牢固,防止破损。防热、防水、防潮。并注意与强酸及食用原料隔离存放。 失火时,可用水、泡沫灭火器或其他灭火装置扑救。

 物化性质 

 白色六角晶系结晶或粉末。无味、无毒、质细腻。相对密度5.606。折射率2.008~2.029。熔点1975℃。溶于酸、氢氧化钠、氯化铵,不溶于水、乙醇和氨水。属两性氧化物。在空气中吸收二氧化碳和水生成碳酸锌呈黄色。加热时变黄,冷却后恢复白色。不透过紫外线,遇硫化氢不变黑。

 质量标准 

 国家标准 gb 3494-83;国家标准 gb/t 3185-92

 分子量 

 81.37

 结构式 

 

 消耗定额 

 湿法氧化锌法 间接法氢碳酸锌法 直接法
锌锭(zn 99.9%) 0.844
粗氧化锌(zno 95%) 1.178
氢氧化锌[zn(oh)2] 1.271
锌灰(折合成纯锌) 0.9
--------------------------------------------------------------------
日本 间接法
锌锭(zn 99.9%) 0.950

 

the product name

 

zno

 

 

product name in english

 

any zinc oxide; any zinc white,

 

 

product alias

 

zinc oxide powder; chinese white

 

 

molecular formula

 

zno

 

 

product use

 

used as a paint and rubber filler

 

 

cas no.

 

1314-13-2

 

 

toxicity of protection

 

poisoning there will be a poor appetite, polydipsia, fatigue, chest tightness, and tenderness, drowsiness, dry cough, and increased body temperature, pupil dilation, conjunctival hyperemia and pharyngeal and face, glucosuria, also sometimes hepatomegaly. followed by pulmonary interstitial edema, alveolar epithelium. poisoning can be inhaled alkaline substance, intravenous glucose (20 ml of 40% solution) and 300 mg of ascorbic acid. according to the symptoms of arm. maximum allowable concentration of 0.5 mg/m3 in the air. operations should wear gas masks, protective glasses, wear overalls. hot water bath after work. attention should be paid to prevent vapor and aerosol formation and discharge to the working place is in the air. dustproof ventilation should be paid attention to.

 

 

packaging and storage and transportation

 

in 2 ~ 3 layers of 80 grams of lined kraft paper or pe plastic woven bag packaging, bags of 25 kg net each, 30 kg. stored in ventilated, cool, dry warehouse. packing should be sealed tightly to prevent breakage. heat protection, waterproof, moistureproof. and pay attention with strong acid and the consumption of raw materials for sequestration. fire, water, foam fire extinguisher or other fire extinguishing device saves.

 

 

physical and chemical properties

 

white hexagonal system crystallization or powder. tasteless, nontoxic, fine quality. relative density of 5.606. refractive index is 2.008 ~ 2.029. melting point is 1975 ℃. soluble in acid, sodium hydroxide, ammonium chloride, insoluble in water, ethanol and ammonia. both sexes oxide. absorb carbon dioxide and water in the air generated carbonic acid zinc yellow. heat the time-varying huang, recover white after cooling. not through the ultraviolet (uv), unchanged in hydrogen sulfide black.

 

 

the quality standard

 

the national standard gb 3494-83; the national standard gb/t 3185-92

 

 

the molecular weight

 

81.37

 

 

structural formula

 

 

 

rate of consumption

 

wet indirect method zinc hydrogen carbonate method, direct method zinc oxide method

 

zinc ingot (99.9% zinc) 0.844

 

1.178 95% crude zinc oxide (zno)

 

1.271 hydrogen zno/zinc (oh) 2]

 

zinc ash (converted into pure zinc) 0.9

 

-- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --

 

the indirect method in japan

 

zinc ingot (99.9% zinc) 0.950

 


 

 

 间接法氧化锌 

分子式:zno      分子量:81.39     cas no:1314-13-2

性状:本产品为白色粉末,比重为5.606,熔点1975 是一种两性氧化物,溶于酸碱、氯化铵和氨水中,不溶于不和乙醇,加热到1800 升华。

用途:供橡胶、涂料、医药、油墨、电缆、电子、造币、搪瓷、火柴、化工、化妆品等工业作原料。

包装:采刚塑料编织袋,内衬塑料薄膜袋包装。

规格:每袋净含量25公斤或50公斤。

质量指标(符合gb/t3185-92)

molecular formula: zno molecular weight: 81.39 cas no: 1314-13-2

 

 

properties: this product is white powder, specific gravity 5.606, melting point 1975 is a kind of amphoteric oxide, soluble in acid and alkali and ammonium chloride and ammonia, ethanol, insoluble in discord, heated to 1800.

 

 

uses: used for rubber, dope, medicine, printing ink, cable, electronics, coinage, enamel, matches, chemical, cosmetics and other industrial raw materials.

 

 

packing: just plastic woven bag, lined with plastic film bag packaging.

 

 

specification: each bag is 25 kg or 50 kg net content.

 

 

quality indicators (in line with the gb/t3185-92)

 

项目

指标

ba01-05(i型)

优级品

氧化锌(zno以干品计)%

 

99.70

金属物(以zn计)%

 

氧化铅(以pb计)%

 

0.157

锰的氧化物(mn计)%

 

0.0001

氧化铜(cu计)%

 

0.0002

盐酸不溶物%

 

0.006

灼烧减量%

 

0.2

筛余物(45um网眼)%

 

0.1

水溶物%

 

0.1

105挥发物%

 

0.3

吸油量 克/100克

 

-

颜色(与标准样比)

 

 

-

消色力(与标准样比)

 

-

 

 

氧 化 锌

序号

指标名称

0号

1号

2号

3号

1

氧化锌(zno)   %≥

99.7

99.5

99

98

2

金属锌(zn  )%≤

0

0

0.008

---

3

氧化铅(pb0)  %≤

0.04

0.06

0.15

---

4

锰(mn)  %≤

0

0

0.0003

---

5

氧化铜(cuo)   %≤

0

0

0.0005

---

6

盐酸不溶物  %≤

0.006

0.008

0.05

---

7

灼烧减量  %≤

0.2

0.2

0.2

---

8

目筛余物(目)

325

200

120

60

9

外观白度(度)  ≥

95

92

90

80

外观及包装:
  有苦味的白色至灰白色粉末,内用塑料袋,外用双层防水压模编织袋,每袋25公斤。

主要用途:
  橡胶制品、涂料、医药、印染、颜料、化妆品、油漆、玻璃制品、瓷釉、化学试剂、、烟火等。

主要特点:
  氧化锌不溶于水,溶于盐酸、硫酸、氢氧化钠和氯化铵溶液,比重5.606,熔点1975摄氏度。

使用说明:
氧化锌使用应防止受潮,不与强酸和碱物存入,不得与食用原料混放,失火时可用水浇救。氧化锌采用直接法和间接法生产,根据不同用途选择产品。

其它说明:
  本产品根据市场行情,实行市场浮动价。

 

氧化锌是一种白色或浅黄色粉末,无毒、无臭。它的密度为5.6/立方米,分子量为81.4,升华温度为1800摄氏度。不溶于水,能溶于强酸和强碱。

   氧化锌的制备方法有三种,即间接法(法国法)、直接法(美国法)和湿化学法。间接法以金属锌锭为原料,把锌锭熔入蒸发坩锅中,经灼热气化通过空气氧化、冷却、捕集得到成品。直接法以含锌的氧化矿为原料,加入煤粉作还原剂,在高温下直接燃烧产生的锌蒸汽与热空气接触氧化生成氧化锌、冷却、捕集得到成品。湿化学法以含锌物料为原料,把原料溶解在硫酸中,经交货获得精制硫酸锌液,加入沉淀剂获得碳酸锌,Zui后焙解得到氧化锌。

   橡胶和轮胎工业是氧化锌的Zui大用户,在橡胶的硫化过程中,能增加橡胶的物理性能。氧化锌也用于油漆、油墨、漆布的着色。它还可以用作润滑油添加剂、水处理和催化剂等化学行业。氧化锌是采用湿化学生产的超细活性氧化锌。它具有大的表面积,能够很好的分散在橡胶中,有害杂质含量低,在橡胶中用量公主间接法氧化锌的50-70%,它的性能指标如下所示:

物理性能:外观:微黄色超细粉体,球形粒子,平均粒径30纳米。0.4-0.5克/毫升。松装密度:比表面积(bet): 40-60平方米/克。筛余物(44微米筛): 小于0.10%。化学分析:zno: 95-98灼伤失重: 小于3%水份: 小于1%cuo (cu)小于0.0005mno (mn)小于0.003pbo (pb)小于0.0001(xrf) xa

appearance and packing:

has a bitter taste of white to gray powder, plastic bags inside, external use double deck waterproof die woven bags, each bag is 25 kg.

main application:

rubber product, paint, medicine, printing and dyeing, paint, cosmetics, senior paint, glass, enamel, chemical reagents, war industry, fireworks, etc.

main features:

zinc oxide is not soluble in water, soluble in hydrochloric acid, sulfuric acid, sodium hydroxide and ammonium chloride solution, specific gravity 5.606, melting point 1975 degrees celsius.

directions for use:

zinc oxide used should prevent be affected with damp be affected with damp, not with acid and alkali content, not with the consumption of raw materials mixed with, when fire with water saving. zinc oxide by direct method and indirect method of production, choose products according to different uses.

other details:

this product according to the market, implement market fudongjia.

zno is a kind of white or light yellow powder, non-toxic, odourless. its density is 5.6 / cubic meter, the molecular weight of 81.4, sublimation temperature is 1800 degrees celsius. insoluble in water, soluble in strong acid and strong alkali.

there are three kinds of preparation methods of zno, the indirect method (france), the direct method (the method) and wet chemical method. indirect method for metal zinc ingot as raw material, melt into the evaporation in the crucible of the zinc ingots by heat gasification of finished product is obtained by air oxidation, cooling and trapping. direct method with zinc oxide ore as raw material, add pulverized coal as reductant, direct combustion at high temperature of zinc vapor in contact with the hot air generated oxide zinc oxide, cooling and trapping for finished products. wet chemical method in zinc material as raw material, the raw material dissolved in acid, the refined zinc sulfate solution, obtained with delivery to join precipitant for zinc carbonate, the roasting zinc oxide solution.

rubber and tire industry is the biggest user of zinc oxide, in the process of rubber vulcanization, can increase the physical properties of rubber. zinc oxide is used in paint, printing ink, varnished cloth color. it can also be used as a chemical industry such as lubricating oil additives, water treatment and catalyst. zinc oxide is produced by wet chemical xihuoxing zinc oxide. it has large surface area, it can well disperse in rubber, low content of harmful impurities in rubber princess dosage of 50-70% of the indirect method zinc oxide, its performance indicators as shown below:

physical properties:

appearance: yellowish superfine powder, spherical particles, the average particle size of 30 nm. 0.4 to 0.5 g/ml.

apparent density:

specific surface area (bet) : 40-60 square metres per gram.

sieve sieve residue (44 microns) : less than 0.10%.

chemical analysis:

zno: 95-98

burns weightlessness: less than 3%

moisture: less than 1%

cuo (cu) is less than 0.0005

mno (mn) is less than 0.003

pbo (pb) is less than 0.0001 (xrf) xa

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本产品的品牌是南华,型号是氧化锌,产品等级是工业级,含量是99.7(%),产商/产地是韶关韶冶,执行质量标准是国标,CAS是优级,规格是间接法

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